May 11, 2020 Comment

Banded-iron formations (BIFs) - Evidence of Oxygen in Early Atmosphere

Our knowledge about the rise of oxygen gas in Earth’s atmosphere comes from multiple lines of evidence in the rock record, including the age and distribution of banded iron formations, the presence of microfossils in oceanic rocks, and the isotopes of sulfur.

However, this article is just focus on Banded Iron Formation.

BIF (polished) from Hamersley Iron Formation, West Australia, Australia

Summary:Banded-iron formations (BIFs) are sedimentary mineral deposits consisting of alternating beds of iron-rich minerals (mostly hematite) and silica-rich layers (chert or quartz) formed about 3.0 to 1.8 billion years ago. Theory suggests BIFs are associated with the capture of oxygen released by photosynthetic processes by iron dissolved in ancient ocean water. Once nearly all the free iron was consumed in seawater, oxygen could gradually accumulate in the atmosphere, allowing an ozone layer to form. BIF deposits are extensive in many locations, occurring as deposits, hundreds to thousands of feet thick. During Precambrian time, BIF deposits probably extensively covered large parts of the global ocean basins. The BIFs we see today are only remnants of what were probably every extensive deposits. BIFs are the major source of the world's iron ore and are found preserved on all major continental shield regions.

Banded-iron formation (BIF) isconsists of layers of iron oxides (typically eithermagnetite orhematite) separated by layers ofchert (silica-rich sedimentary rock). Each layer is usually narrow (millimeters to few centimeters). The rock has a distinctively banded appearance because of differently colored lighter silica- and darker iron-rich layers. In some cases BIFs may containsiderite (carbonate iron-bearing mineral) or pyrite (sulfide) in place of iron oxides and instead of chert the rock may contain carbonaceous (rich in organic matter)shale.

It is a chemogenic sedimentary rock (material is believed to be chemically precipitated on the seafloor). Because of old age BIFs generally have been metamorphosed to a various degrees (especially older types), but the rock has largely retained its original appearance because its constituent minerals are fairly stable at higher temperatures and pressures. These rocks can be described as metasedimentary chemogenic rocks.

Jaspilite banded iron formation (Soudan Iron-Formation, Soudan, Minnesota, USA

Image Credits: James St. John

In the 1960s, Preston Cloud, a geology professor at the University of California, Santa Barbara, became interested in a particular kind of rock known as a Banded Iron Formation (or BIF). They provide an important source of iron for making automobiles, and provide evidence for the lack of oxygen gas on the early Earth.

Cloud realized that the widespread occurrence of BIFs meant that the conditions needed to form them must have been common on the ancient Earth, and not common after 1.8 billion years ago. Shale and chert often form in oceanenvironments today, wheresediments and silica-shelled microorganisms accumulate gradually on theseafloor and eventually turn into rock. But iron is less common in younger oceanicsedimentary rocks. This is partly because there are only a few sources of iron available to the ocean: isolated volcanic vents in the deep ocean and material weathered from continental rocks and carried to sea by rivers.

Banded iron-formation (10 cm), Northern Cape, South Africa.

Specimen and photograph: A. Fraser

Most importantly, it is difficult to transport iron very far from these sources today because when iron reacts with oxygengas, it becomesinsoluble (it cannot be dissolved in water) and forms asolid particle. Cloud understood that for large deposits of iron to exist all over the world’s oceans, the iron must have existed in a dissolved form. This way, it could be transported long distances in seawater from its sources to the locations where BIFs formed. This would be possible only if there were little or no oxygen gas in the atmosphere and ocean at the time the BIFs were being deposited. Cloud recognized that since BIFs could not form in the presence of oxygen, the end of BIF deposition probably marked the first occurrence of abundant oxygen gas on Earth (Cloud, 1968).

Cloud further reasoned that, for dissolved iron to finallyprecipitate and be deposited, the iron would have had to react with small amounts of oxygen near the deposits. Small amounts of oxygen could have been produced by the first photosynthetic bacteria living in the open ocean. When the dissolved iron encountered the oxygen produced by the photosynthesizing bacteria, the iron would have precipitated out of seawater in the form ofminerals that make up the iron-rich layers of BIFs: hematite (Fe2O3) and magnetite (Fe3O4), according to the following reactions:

4Fe3 + 2O2 → 2Fe2O3

6Fe2 + 4O2 → 2Fe3O4

The picture that emerged from Cloud’s studies of BIFs was that small amounts of oxygengas, produced by photosynthesis, allowed BIFs to begin forming more than 3 billion years ago. The abrupt disappearance of BIFs around 1.8 billion years ago probably marked the time when oxygen gas became too abundant to allow dissolved iron to be transported in the oceans.

Banded Iron Formation

Source is unknown

It is interesting to note that BIFs reappeared briefly in a few places around 700 millionyears ago,during a period of extremeglaciation when evidence suggests that Earth’s oceans were entirely covered with sea ice. This would have essentially prevented the oceans from interacting with theatmosphere, limiting the supply of oxygengas in the water and again allowing dissolved iron to be transported throughout the oceans. When the sea ice melted, the presence of oxygen would have again allowed the iron toprecipitate.

References:

1. Misra, K. (1999). Understanding Mineral DepositsSpringer.

2. Cloud, P. E. (1968). Atmospheric and hydrospheric evolution on the primitive Earth both secular accretion and biological and geochemical processes have affected Earth’s volatile envelope.Science, 160(3829), 729–736.

3. James,H.L. (1983). Distribution of banded iron-formation in space and time.Developments in Precambrian Geology, 6, 471–490.

May 09, 2020 Comment

The Messinian Salinity Crisis

You will have heard of The Messinian Salinity Crisis no doubt. From learned articles, geology textbooks, probably lectures at your college or University. Or possibly not. This was not always the hot topic it is now. In fact, the very idea of this happening, was for a while, challenged, even ridiculed. It seemed too incredible that this could happen as it did and Dessication/Flood theories took time to gain traction. But, if you had heard about it, you would remember that The Messinian Salinity Crisis, was a time when the Mediterranean Sea, very much as we know it today, evaporated – dried out, almost completely.

You will have heard of the rates of desiccation, influx and yet more desiccation, repeated in endless cycles over tens, even hundreds of thousands of years. On a human temporal scale, this would have been a long drawn out affair, covering a time hundreds of generations deep, more than the span of Homo sapiens existence. In Geologic terms however, it was a string of sudden events. Of incredibly hot and arid periods followed by rapid ingress of waters, either via spillways through what is now modern day Morocco and the southern Iberian peninsular, or headlong through a breach in the sill between the Pillars of Heracles, the modern day Straights of Gibraltar.

There were prolonged periods of dessication, of desolate landscapes beyond anything seen today in Death Valley or The Afar Triangle. These landscapes were repeatedly transgressed by brackish waters from storm seasons far into the African and Eurasian interiors, or the Atlantic, and these in turn dried out. Again and again this happened. It had to be so because the vast deposits of rock salt, gypsum and anhydrites could not have been emplaced in a single evaporite event. The salt deposits in and around the Mediteranean today represent fifty times the current capacity of this great inland sea. You may have heard too of the variety of salts production, as agglomerating crystals fell from the descending surface to the sea floor, or as vast interconnected hypersaline lakes left crystalline residues at their diminishing margins, as forsaken remnant sabkhas, cut off from the larger basins, left behind acrid dry muds of potassium carbonates – the final arid mineral residue of the vanished waters.

Just under six million years ago, Geologic processes isolated what was left of the ancient Tethys ocean, the sea we know as the Mediterranean, home to historic human conflicts and marine crusades of Carthage, Rome, Athens and Alexandria, a Sea fringed by modern day Benidorm, Cyprus, Malta and Monaco. At a time 5.96 million years ago – evaporation outpaced replenishment. Indeed, just as it does today, but without the connecting seaway to replenish losses. Inexorable tectonic activity first diverted channels, then – sealed them. Cut off from the Atlantic in the West, water levels fell, rose briefly and fell again, and again. The mighty Nile - a very different geophysical feature of a greater capacity than today, and the rivers of Europe cut down great canyons hundreds and thousands of metres below present Eustatic sea and land surface levels, as seismic cross sections show in staggering detail. The cores taken at depth in the Mediterranean, show Aeolian sands above layers of salt, fossiliferous strata beneath those same salts, all indicating changing environments. The periods of blackened unshifting desert varnished floors and bleached playas, decades and centuries long, were punctuated often by catastrophic episodes, with eroded non conformable surfaces of winnowed desert pavement, toppled ventifracts, scours and rip up clasts. Species of fossilised terrestrial plant life, scraping an arid existence have been found, thousands of meters down, in the strata of the Mediterranean sea floor.

There is much evidence too, in the uplifted margins of Spain, France, and Sicily, of those hostile millennia when the sea disappeared. Incontrovertible evidence, painstakingly gathered, analysed and peer reviewed, demonstrates via the resources of statistical analysis, calculus and geophysical data that the Messinian Salinity Crisis was a period during the Miocene wherein the geology records a uniquely arid period of repeated partial and very nearly complete desiccation of the Mediterranean Sea over a period of approximately 630,000 years. But for the Geologist, the story doesn’t end there. The Geologists panoptic, all seeing third eye, sees incredible vistas and vast panoramas. Of a descent from the Alpine Foreland to the modern day enclave of Monaco, gazing out southwards from a barren, uninhabited and abandoned raised coast to deep dry abyssal plains, punctuated by exposed chasms, seamounts and ridges, swirling and shifting so slowly in a distant heat haze. A heat haze produced by temperatures far above any recorded by modern man and his preoccupation with Global Warming. An unimaginable heat sink would produce temperatures of 70 to 80 degrees Celsius at 4000M depth within the basins.

Looking down upon this Venusian landscape, the sun might glint on remaining lakes and salt flats so very far away and so very much farther below. Hills and valleys, once submerged, would be observed high and dry – from above, as would the interconnecting rivers of bitter waters hot enough to slowly broil any organism larger than extremophile foraminifer. All this, constantly shimmering in the relentless heat. Only the imagination of the geologist could see the vast, hellish, yet breathtaking landscape conjured up by the data and the rock record. And finally, the Geologist would visualise a phenomenon far greater in scope and magnitude than any Biblical flood – The Zanclean Event.

Also known as The Zanclean Deluge, when the drought lasting over half a million years was finally ended as the Atlantic Ocean breached the sill/land bridge between Gibraltar and North West Africa. Slowly perhaps at first until a flow a thousand times greater than the volumetric output of the Amazon cascaded down the slopes to the parched basins. Proximal to the breach, there would be a deafening thunderous roar and the ground would tremor constantly, initially triggering great avalanches above and below the Eustatic sea level as the far reaching and continuous concussion roared and rumbled on, and on, and on. For centuries great cataracts and torrents of marine waters fell thousands of metres below and flowed thousands of kilometers across to the East. Across to the abyssal plains off the Balearics, to the deeps of the Tyrrhenian and Ionian seas, into the trenches south of the Greek Islands and finally up to the rising shores of The Lebanon. The newly proximal waters to the final coastal reaches and mountains that became islands, must have had a climatological effect around the margins of the rejuvenated Mediterranean. Flora and Fauna both marine and terrestrial will have recolonised quickly. Species may have developed differently, post Zanclean, on the Islands. And in such a short period, there must surely have been earthquakes and complex regional depression and emergence. Isostacy compensated for the trillions of cubic meters of transgression waters that now occupied the great basins between the African and Eurasian plates, moving the land, reactivating ancient faults and within and marginal to the great inland sea, a region long active with convergent movements of a very different mechanism.

Hollywood and Pinewood have yet to match the imagination of the Earth Scientist, of the many chapters of Earths dynamic history held as fully tangible concepts to the men and women who study the rocks and the stories they tell. The movies played out in the mind of the geologist are epic indeed and – as we rightly consider the spectre of Global Warming, consider too the fate of future populations (of whatever evolved species) at the margins of the Mediterranean and the domino regions beyond, when inexorable geologic processes again isolate that benign, sunny holiday sea. Fortunately, not in our lifetime, but that of our far off descendants who will look and hopefully behave very differently from Homo Sapiens.

Note: This blog is written and contributed by Paul Goodrich. You can also contribute your blog or article on our website. See guidelineshere.